Rice husk ash (RHA): A Highly efficient solid acid catalyst for the oxidation of alcohols and trimethylsilyl, tetrahydropyranyl and methoxymethyl ethers with CrO3
نویسندگان
چکیده مقاله:
A mild, efficient and fast method for the oxidation of alcohols and trimethylsilyl, tetrahydropyranyl and methoxymethyl ethers to their corresponding carbonyl compounds using CrO3 in the presence of rice husk ash (RHA) is reported. All reactions were performed at room temperature in high to excellent yields. A new, efficient and green catalyst, heterogeneous reaction conditions, easy work-up of the products and high reaction rates are the main advantages of this method.
منابع مشابه
rice husk ash (rha): a highly efficient solid acid catalyst for the oxidation of alcohols and trimethylsilyl, tetrahydropyranyl and methoxymethyl ethers with cro3
a mild, efficient and fast method for the oxidation of alcohols and trimethylsilyl, tetrahydropyranyl and methoxymethyl ethers to their corresponding carbonyl compounds using cro3 in the presence of rice husk ash (rha) is reported. all reactions were performed at room temperature in high to excellent yields. a new, efficient and green catalyst, heterogeneous reaction conditions, easy work-up of...
متن کاملRapid oxidation of alcohols and trimethylsilyl and tetrahydropyranyl ethers with CrO3 in the presence of sulfonic acid functionalized ordered nanoporous Na+-montmorillonite
A mild, efficient and fast method for the oxidation of alcohols and trimethylsilyl and tetrahydropyranyl ethers to their corresponding carbonyl compounds using CrO3 in the presence of sulfonic acid functionalized ordered nanoporous Na+-montmorillonite (SANM) and under solvent-free conditions is reported. All reactions were performed at room temperature in high to excellent...
متن کاملRapid oxidation of alcohols and trimethylsilyl and tetrahydropyranyl ethers with CrO3 in the presence of sulfonic acid functionalized ordered nanoporous Na+-montmorillonite
A mild, efficient and fast method for the oxidation of alcohols and trimethylsilyl and tetrahydropyranyl ethers to their corresponding carbonyl compounds using CrO3 in the presence of sulfonic acid functionalized ordered nanoporous Na+-montmorillonite (SANM) and under solvent-free conditions is reported. All reactions were performed at room temperature in high to excellent...
متن کاملIntroduction of sulfonated rice husk ash as a highly efficient reusable catalyst for the protection of the hydroxyl group
A mild, efficient and fast method for the trimethylsilyl (TMS), tetrahydropyranyl (THP) and methoxymethyl (MOM) protection of alcohols and phenols in the presence of sulfonated rice husk ash (RHA-SO3H) is reported. All reactions were performed at room temperature in high to excellent yields. All the products are separated and compared with authentic samples and/ or identified using different ty...
متن کاملIntroduction of sulfonated rice husk ash as a highly efficient reusable catalyst for the protection of the hydroxyl group
A mild, efficient and fast method for the trimethylsilyl (TMS), tetrahydropyranyl (THP) and methoxymethyl (MOM) protection of alcohols and phenols in the presence of sulfonated rice husk ash (RHA-SO3H) is reported. All reactions were performed at room temperature in high to excellent yields. All the products are separated and compared with authentic samples and/ or identified using different ty...
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عنوان ژورنال
دوره 5 شماره 3
صفحات 223- 230
تاریخ انتشار 2015-09-01
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